Biocidal Activities of a New Type of Polysaccharide (Extract from Egyptian Aloe Vera)-Based Cationic Schiff Bases Surfactant and Their Metal Complexes
Petroleum Science and Engineering
Volume 2, Issue 1, June 2018, Pages: 37-43
Received: Apr. 1, 2018; Accepted: Apr. 19, 2018; Published: May 19, 2018
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Authors
Mostafa E. Hendawy, Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mohammed F. Zaky, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Abdelfattah M. Badawi, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Ibrahim A. Sabbah, Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
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Abstract
Five series of cationic polysaccharide Schiff bases surfactant [AQ10-18] were synthesized by the reaction between different five Schiff bases (which prepared by condensation of fatty amine namely: decyl, dodecyl, tetradecyl, hexadecyl and octadecyl amine and 4-pyridine carboxaldehyde) and polysaccharide sulfate as quaternizing agent. Also, their complexes with different transition metals including Ni2+, Co2+, Cu2+ and Fe3+ were synthesized. The chemical structures of these surfactants were confirmed using elemental analysis, FTIR spectra, UV spectra, 1H-NMR and atomic absorption spectroscopy. The studied surfactants were evaluated as antimicrobial agents against pathogenic and sulfate reducing bacteria using inhibition zone diameters. The synthesized cationic polysaccharide Schiff bases surfactant showed good antimicrobial activities against the tested microorganisms including Gram positive, Gram negative, yeast and fungi. The effect of the structure of these cationic surfactants and their metal complexes of Ni2+, Co2+, Cu2+ and Fe3+ on the cell membrane is discussed as well as their potent action on the targeted bacteria, yeast and fungi.
Keywords
Antimicrobial Activity, Carbohydrate Esters, Cationic Surfactants, Polysaccharide Schiff Bases Surfactant, Biocidal Activity
To cite this article
Mostafa E. Hendawy, Mohammed F. Zaky, Abdelfattah M. Badawi, Ibrahim A. Sabbah, Biocidal Activities of a New Type of Polysaccharide (Extract from Egyptian Aloe Vera)-Based Cationic Schiff Bases Surfactant and Their Metal Complexes, Petroleum Science and Engineering. Vol. 2, No. 1, 2018, pp. 37-43. doi: 10.11648/j.pse.20180201.16
Copyright
Copyright © 2018 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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