Petroleum Science and Engineering
Volume 2, Issue 1, June 2018, Pages: 7-16
Received: Mar. 20, 2018;
Accepted: Mar. 30, 2018;
Published: May 7, 2018
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Chika Muhammad, Department of Pure and Applied Chemistry, Faculty of Science, Usmanu Danfodiyo University, Sokoto, Nigeria
Zaliha Usman, Department of Pure and Applied Chemistry, Faculty of Science, Usmanu Danfodiyo University, Sokoto, Nigeria
Francis Agada, Department of Pure and Applied Chemistry, Faculty of Science, Usmanu Danfodiyo University, Sokoto, Nigeria
Due to the environmental problems caused by the use of fossil fuels, considerable attention has been given to biodiesel production as an alternative to petrol diesel. Biodiesel is ecofriendly, alternative diesel fuel prepared from domestic renewable sources that is, from vegetable oils and animal fats. It is a renewable source of energy which seems to be an ideal solution for global energy demand. In this study, the biodiesel production from kapok (Ceiba pentandra) seed oil with methanol has been considered in the presence of catalyst that is, CaO derived from snail shell. Optimum yield conditions were determined experimentally by changing certain parameters such as reaction time and temperature, at the end of the experiment, the maximum yield of 56.7 % was obtained at 60°C and reaction time of 60 minutes. The physicochemical properties of the produced biodiesel were determined by ASTM procedures and were found to be comparable to ASTM standards for diesel fuel except for acid value which was above the recommended standard. Gas Chromatography-Mass Spectroscopy (GC-MS) demonstrated the presence of hydrocarbons.
Biodiesel Production from Ceiba pentandra Seed Oil Using CaO Derived from Snail Shell as Catalyst, Petroleum Science and Engineering.
Vol. 2, No. 1,
2018, pp. 7-16.
Kathirvelu S., Shenbaga V. M. N., Neela K., Mayilsamy K and Krishnaswamy. (2014). ARPN Journal of Engineering and Applied Science: www.arpnjournals.com
Muktar, M., Muhammad, C., Dabai, M. U. and Mamuda, M. (2015). Ethanolysis of Calabash (Lageneria sinceraria) Seed Oil for The Production of Biodiesel. American Journal of Energy Engineering. 2(6): 141-145.
Barnwal, B. K and Sharma, M. P. (2005). Prospect of Biodiesel Production from.
Ramadhas A. S., Jayaraj S. and Muraleedharan C. (2004). Use of Vegetable Oil as I. C. Engine fuels- A Review. Renewable Energy. 29:727-742.
Hanny J. B and Shizuko H. (2008). Biodiesel Production from Crude Jatropha Curcas L. Seed Oil with a High Content of Free Fatty Acids. Bioresource Technology. 99: 1716-1721.
Endah, M., Marhaeni, P., Rachimoellah, M., Nidya, S. and Ferdy, P. (2012). Global Journal of Researches in Engineering, Chemical Engineering. 12(2): Version 10.
Chojnaka, K. (2005). “Bioabsorption of Cr(III) Ions by Egg Shells. Journal of Hazardous Material. 121:167-173.
Sulaiman S., Syakirah, Khairudin N., Jamal P. and Alam M. Z. (2015). “Fish Bone Waste as Catalyst for Biodiesel Production”. Journal of Tropical Resources and Sustainable Science. 3: 180-184.
Viriya-Empikul N, Krasae P, Puttasawat B, Yoosuk B, Chollacoop N and Faungnawakij K. (2010). Waste Shell of Mollusk and Egg as Biodiesel Production Catalysts, Bioresour Technol: 101(10): 3765-7.
Nakatani, N., Takamori, H., Takeda, K. and Sakugawa, H. (2009). “Transesterification of Soybean Oil Using Combusted Oyster Shell Waste as a Catalyst”. Bioresource Technology. 100: 1510-1513.
Rezaei, R., Mohadesi, M. M. and Moradi, G. R. (2013). “Optimization of Biodiesel Production Using Waste Mussle Shell Catalyst”. Fuel. 109: 534-541.
Mohan S. K. (2015). Studies on Optimization of Biodiesel Production- Snail Shell as Eco-Friendly Catalyst by Transesterification of Neem Oil.
Hossain, S. A., Salleh, B. M,. Boyce, A., Chowdhury, A. N. and Naqiuddin, M. (2008). Biodiesel Fuel Production from Algae as Renewable Energy. American Journal of Biochemistry and Biotechnology. 4(3):250-251.
Gandure, J., Ketlogetwe, C. and Temu, A. (2013). Fuel Properties of Jatropha Methyl Ester and Its Blends with Petroleum Diesel. Journal of Engineering and Applied Science. 8(11): 900-903.
Ved, K. and Padam, K. (2013). Study of Physicochemical Properties of Biodiesel from Sorghum Oil. Research Journal of Chemical Sciences. 3(9):64-67.
Akpan U. G., Jimola A. and Mohammed A. D. (2006). Extraction, Characterization and M, odification Of Castor Seed Oil. Leonardo Journal of Science. 8: 43–52.
Birnin-Yauri, A. U. and Garba, S. (2011). Comparative Studies on Some Physicochemical Properties of Baoba, Vegetable, Peanut and Palm Oils. Nigerian Journal of Basic and Applied Science. 19(1): 64–67.
Awab W. Al-Harbawy and Mozahim K. Al-Mallah (2014). Prtoduction and Characterization of Biodiesel from seed oil of Castor (Ricinus communis L.) plant, IJST 3(9) 508-513.
Heroor, S. H. and Rahul, S. D. (2013). Production of Biofuel from Crude Neem Oil and It Performance. International Journal of Environment Engineering and Management. 4(5): 425-432.
Salaheldeena, M., Aroua, M. K and Mariod, A. A. (2015). Physicochemical Characterization and Thermal Behavior of Biodiesel and Biodiesel-Diesel Blends Derived from Crude Moringa Peregrina seed Oil. Journal of Energy Conversion and Management. 92: 532-542.
Demirbas, A. (2008). Biodiesel from Vegetable Oils Via Esterification in Supercritical Methanol. Energy Conversion Management. 43(23):49-56.
Sokoto, A. M., Hassan, L. G. and Dangoggo, S. M. (2011). Influence of Fatty Acid Methyl Ester On Fuel Properties Of Biodiesel Produced From Curcubitapopo. Nigerian Journal of Basic Applied Science. 19:81-86.
Gerpen, J. V., Shanks, B., Pruszko, R., Clement, D. and Knothe, G. (2004). Biodiesel Production Technology. National Renewable Energy Laboratory, 1617 Cole Boulevard; Colorado. USA. Pp 22-28.
Indhumathi, P., Shabudeen, P. S. and Shoba, U. S. (2014). A Method for Production and Characterization of Biodiesel from Green Micro Algae. International Journal of Bio-Science and Bio-Technology. 6(5): 111–122.
Thirumarimurugan, M., Sivakumar, V. M., Xavier, A. M., Prabhakaran, D. and Kannadasan, T.(2012). Preparation Of Biodiesel From Sunflower Oil By Transesterification. International Journal of Bioscience and Bioinformations.2(6): 441–444.
American Standard for Testing and Materials (ASTM). (1998). Standard Test Method for Sulphur in Petroleum and Petroleum Products By Energy Dispersive X-ray Flourescence Spectrometry, Annual Book of ASTM Standards. 5(3): 805-808.
Muhammad, C., Ladan, M. J. and Wasagu R. U. S. (2006). Comparative Analyses of Vegetable Oils Sold in Bodinga, Sokoto State, Nigeria. Biological and Environmental Science Journal for The Tropics. 3(1): 113-116.
Muthu, H., Sathyaselvabala, V., Varathachary, T., KiruphaSelvaraj, D., Nandagopal, J., and Subramanian, S. (2010). Synthesis of Biodiesel from Neem Oil by Two-Step Tranesterification. Braziliian Journal of Chemical Engineering. 27(4): 601- 608.
Fakhary, E. M. And El-Maghraby, D. M. (2013). Fatty Acids Composition and Biodiesel Characterization of Dunaliella Salina. Journal of Water Resource and Protection. 5: 894–899.
Mukhtar, M. and Dabai, M. U. (2016). Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari Macrophylla) Seed Oil Using MgO/Al2O3 Catalyst. American Journal of Environmental Protection. 5(5): 128-133.
Garcia J., Lopez T., Alvarez M., Aguilar D. H. and Quintana P. (2008). “Spectroscopic, Structural and Textural Properties of CaO-SiO2 Materials Synthesized by Sol-gel with Different Acid Catalysts”. Journal of Non-Crystalline Solids. 354(2-9): 729-732.
Galvan-Ruiz, M., Hernandez, J., Banos, L., Noriega- Montes J., Mario E. and Rodriguez (2009). “Characteristics of Calcium Carbonate, Calcium Oxide and Calcium Hydroxide as Starting Point to The Improvement of Lime for their Use In Construction”. Journal of Materials in civil Engineering. 21(11): 694-698
Tan Y. H., Abdullah M. O., Nolasco-Hipolito C. and Taufiq-Yap Y. H. (2015). “Waste Ostrich and Chicken Eggshells as Heterogeneous Base Catalyst for Biodiesel Production Fron Cooking Oil: Catalyst Characterization and Biodiesel Yield Performance”. Journal of Applied Energy. 160:58-70.