Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped
International Journal of Science and Qualitative Analysis
Volume 2, Issue 3, November 2016, Pages: 36-40
Received: Oct. 27, 2016; Accepted: Nov. 10, 2016; Published: Dec. 30, 2016
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Authors
Gharibi El Khadir, Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco
Hatim Oumaima, Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco
El Bekkaye Yousfi, Superior Institution of Health Professions and Nursing Techniques, Oujda, Morocco
Oumnih Safae, Chemistry Laboratory of Solid mineral and Analytical, Faculty of Science, Oujda, Morocco
Abou-salama Mohamed, Multidisciplinary Faculty of Nador, Nador, Morocco
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Abstract
In this work we have synthesized Li (Ni1/3Co1/3Mn1/3) O2 using sulfates metals Ni, Co and Mn and LiCl salt. The used method is easy and led to yield higher than 75%. Identification and lamellar α-type NaFeO2 of the composite synthesized were demonstrated by X-ray diffraction and FTIR spectroscopy. We demonstrated that the product is pure and its crystallinity changes according to the parameters of the annealing step. The electronic structure of the compound has been modified by doping with monovalent Cupper cation. The results are encouraging and show that the lamellar structure is not altered. We noticed an increase in infill distances that can affect the mobility of lithium cations during the insertion cycles / extraction. Indeed, the charge on the surface of the doped product is -90mV after 60 minutes and that of the undoped compound is -241mV.
Keywords
Li (Ni1/3Co1/3Mn1/3) OH2, Battery Li-ion, LiCoO2, α-Type Layer NaFeO2
To cite this article
Gharibi El Khadir, Hatim Oumaima, El Bekkaye Yousfi, Oumnih Safae, Abou-salama Mohamed, Elaboration and Characterization of Li (Ni1/3Co1/3Mn1/3) O2 Intrinsic and Cu Doped, International Journal of Science and Qualitative Analysis. Vol. 2, No. 3, 2016, pp. 36-40. doi: 10.11648/j.ijsqa.20160203.13
Copyright
Copyright © 2016 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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