Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry
American Journal of Heterocyclic Chemistry
Volume 4, Issue 1, March 2018, Pages: 22-25
Received: Oct. 18, 2017;
Accepted: Nov. 23, 2017;
Published: Jan. 29, 2018
Views 1236 Downloads 113
Mikayilova Mexriban Rahil, Scientific-Research Laboratory «New Chemical Materials and Technologies», "Azerbaijan State University of Oil and Industry", Baku, Republic of Azerbaijan
Mustafayeva Rena Eldar, Scientific-Research Laboratory «New Chemical Materials and Technologies», "Azerbaijan State University of Oil and Industry", Baku, Republic of Azerbaijan
Follow on us
Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.
Complex Compounds, Ruthenium, Nicotinic Acid Amide, Donor Ligands, Palladium
To cite this article
Mikayilova Mexriban Rahil,
Mustafayeva Rena Eldar,
Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry, American Journal of Heterocyclic Chemistry.
Vol. 4, No. 1,
2018, pp. 22-25.
Copyright © 2018 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/
) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Raevskaya MV: Physicochemistry of ruthenium and its alloys / MV Raevskaya // Chemistry of ruthenium, rhodium, palladium, osmium, iridium, platinum, per. With the English. M.: 1979.-P. 138-140.
Brockhaus F. A. Encyclopedic Dictionary Brockhaus and I. A. Efron / F. A. Brockhaus, I. A. Efron. - S.-Pb.: Brockhaus - Efron, 1890-1907.-347 p.
Prokhorov A. M. Physical encyclopedia in 5 volumes / А. М. Prokhorov, Moscow: Soviet Encyclopedia. Editor-in-chief A. M. Prokhorov. - Volume 3, p. 317-319.
Sokolov I. V. Popular library of chemical elements / I. V. Petryanov-Sokolov // Moscow: Nauka Publishers, 1963. pp. 83-86.
M. Cavazzini, S. Quici, C. Scalera, F. Puntoriero, G. La Ganga, S. Campagna. Synthesis, characterization, absorption spectra, and luminescence properties of multinuclear species made of Ru (II) and Ir (III) chromophores. // Inorg. Chem.-2009.-V. 48.-P. 8578-8592.
R. Lalrempuia, M. R. Kollipara. Rectivity studies of η6-arene ruthenium (II) dimers with polypyridyl ligands: isolation of mono, binuclear p- cymene ruthenium (II) complexes and bisterpyridine ruthenium (II) complexes. //Polyhedron-2003.-V. 22.-P. 3155-316.
C. Mikel, P. G. Potvin. Synthesis and enhanced photosensitization ability of a 4-carboxy-2, 2′:6′, 2″- terpyridine complex of ruthenium (II)// Polyhedron-2002.-V. 21.-P. 49-54.
J. Mola, E. Mas-Marza, X. Sala, I. Romero, M. Rodriguez, C. Vinas, T. Parella, A. Llobet. Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports. // Angew. Chem. Int. Ed.-2008.-V. 47.-P. 5830-5832.
M. Agaguseynova, N. E. Jabbarova Coordination compounds of transition metals in catalysis.// Chem. Soc. Commun. Baku-2006 -p. 129-135.
M. Agaguseynova, N. E. Jabbarova Complexes of transition metals with molecular oxygen.// Chem. Soc. Commun. Baku-2012 -p. 96-111.