Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst
American Journal of Heterocyclic Chemistry
Volume 1, Issue 1, April 2015, Pages: 6-12
Received: Apr. 10, 2015; Accepted: Apr. 22, 2015; Published: Apr. 28, 2015
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Authors
Ali Gharib, Department of Chemistry, Islamic Azad University, Mashhad, Iran; Department of Chemistry, Agricultural Researches and Services Center, Mashhad, Iran
Nader Noroozi Pesyan, Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran
Leila Vojdani Fard, Education Ministry, Education Organization of Razavi Khorasan, Mashhad, Iran
Mina Roshani, Department of Chemistry, Islamic Azad University, Mashhad, Iran
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Abstract
Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.
Keywords
Pyrazoline, Nanoparticles, Preyssler, Heteropolyacids, Catalyst, Synthesis
To cite this article
Ali Gharib, Nader Noroozi Pesyan, Leila Vojdani Fard, Mina Roshani, Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst, American Journal of Heterocyclic Chemistry. Vol. 1, No. 1, 2015, pp. 6-12. doi: 10.11648/j.ajhc.20150101.12
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