Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules
American Journal of Polymer Science and Technology
Volume 2, Issue 2, November 2016, Pages: 47-53
Received: Sep. 16, 2016; Accepted: Nov. 2, 2016; Published: Jan. 13, 2017
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Mauricio Guilherme Vieira, Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Angélica Machi Lazarin, Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
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This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.
Inorganic Compounds, Chemical Synthesis, Adsorption, Preconcentration
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Mauricio Guilherme Vieira, Angélica Machi Lazarin, Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules, American Journal of Polymer Science and Technology. Vol. 2, No. 2, 2016, pp. 47-53. doi: 10.11648/j.ajpst.20160202.15
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