Synthesis and Characterization of a High Oil-Absorbing Poly (Methyl Methacrylate-Butyl Acrylate)/ATP–Fe3O4 Magnetic Composite Material
American Journal of Polymer Science and Technology
Volume 2, Issue 1, September 2016, Pages: 1-10
Received: Jul. 10, 2016; Accepted: Aug. 19, 2016; Published: Aug. 30, 2016
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Authors
Fathelrahman Mohammed Soliman, Analytical Chemistry (Functional Materials), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China; Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wu Yang, Analytical Chemistry (Functional Materials), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Hao Guo, Analytical Chemistry (Functional Materials), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Mahgoub Ibrahim Shinger, Analytical Chemistry (Photocatalysis), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, china
Ahmed Mahmoud Idris, Analytical Chemistry (Photocatalysis), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, china
Emtenan Suliman Hassan, Analytical Chemistry (Functional Materials), College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
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Abstract
A highly oil-absorptive Poly (methyl methacrylate-butyl acrylate)/ ATP–Fe3O4 magnetic composite resin was prepared by a conventional suspension polymerization using methyl methacrylate, and butylacrylate were used as monomers, and N, N-methylenebis acrylamide (MBA) as crosslinking agent and ammonium persulfate (APS) as initiator on the modified ATP–Fe3O4substrate. The optimum reaction condition was examined in detail. The results indicated that the prepared composite resin combined characteristics of stronger magnetism and higher oil absorbency. The resultant resin had high oil absorbency and the highest absorbencies respectively reaches 23.8, 25, 30.0, 32.6g.g for xylene, toluene, carbon tetrachloride and chloroform, which were higher than some oil absorptive materials previously reported. At the same time, it could easily be recovered and reused too. Kinetic investigation proved that the oil absorption obeyed the pseudo-first-order kinetic model and intraparticle diffusion model.
Keywords
High Oil-Absorption, Magnetic Composite Resin, Modified ATP–Fe3O4
To cite this article
Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Emtenan Suliman Hassan, Synthesis and Characterization of a High Oil-Absorbing Poly (Methyl Methacrylate-Butyl Acrylate)/ATP–Fe3O4 Magnetic Composite Material, American Journal of Polymer Science and Technology. Vol. 2, No. 1, 2016, pp. 1-10. doi: 10.11648/j.ajpst.20160201.11
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Copyright © 2016 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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