The Ability of Anilines Extracted from Iraqi Petrol on Preventing Deposits Formation in Crude Kerosene
International Journal of Oil, Gas and Coal Engineering
Volume 3, Issue 1, January 2015, Pages: 13-17
Received: Mar. 14, 2015; Accepted: Mar. 27, 2015; Published: Apr. 9, 2015
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Author
Mohammad Jamil Abd Al-Ghani, General Science Department, Collage of Basic Education, University of Salah Al- Din, Iraq- Erbil
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Abstract
The oxidative degradation products formed under both the prolonged storage and thermal stress are a problem in the utilization of Kerosene fuels. Researchers are directed in developing fuel stabilizers that are increasingly cost-effective, do not degrade the performance of fuel and are environmentally acceptable. Our interest in anilines extracted from Iraqi crude oil has led to evidence that they are excellent antioxidant stabilizers for tetraline at elevated temperatures. The results of stability experiments for thermal and oxidative degradation of two crude Kerosene fuel samples obtained from al-Dora refinery with 0.20% sulfur contents (sample A), and from Kirkuk refinery with 0.25% sulfur contents (sample B) were evaluated in these stability tests in comparison with other well-known stabilizers. The samples were treated as follows: 1.They subjected to long period of storage (90 days) without any additives. 2. They exposed to thermal aging at elevated temperature (393K) without any additives for 3 hours. Chemical factors preventing formation of color, insoluble sediments and gums were studied by modeling generally accepted degradation mechanisms. In this paper we will report our mechanistic investigation into the chemical details of the stabilization and effect of chemical structure of extracted N,N-P-methyl phenyl acetone (MPA) and N, N- phenyl acetone (PA)on the activity of deposits formation in kerosene in a comparison with 2, 6-di-t-butyl-4- methyl phenol (Unol), and tertiary alkyl primary aniline (TAPA) with 9, and 12 carbon atoms.
Keywords
Kerosene, Stability, Degradation, Deposits
To cite this article
Mohammad Jamil Abd Al-Ghani, The Ability of Anilines Extracted from Iraqi Petrol on Preventing Deposits Formation in Crude Kerosene, International Journal of Oil, Gas and Coal Engineering. Vol. 3, No. 1, 2015, pp. 13-17. doi: 10.11648/j.ogce.20150301.12
References
[1]
Philippe Dagaut, mechhel cathonnet, "the ignition, oxidation and combustion of Kerosene" Journal of Energy and Combustion Sceince, 32(1), 2006, (48-92).
[2]
H. A. Spikes "The History and Mechanisms of antioxidants," Tribology Letters, 17(3), 469 (2006).
[3]
J. R. Lindsay Smith, E. Nagatomi, D. J. Waddington, “The Autoxidation of petroleum products. Journal of the Chemical Society Perkin Transactions 2, (11), (2000) 2248.
[4]
S. B. Saville, F. D. Gainey, S. D. Cupples, M. F. Fox and D. J. Picken, “A Study of Lubricant Condition in the Piston Ring Zone of Single Cylinder Diesel Engines Under Typical Operating Conditions”, SAE Technical Paper 881586, International Fuels and Lubricants Meeting, Oct 10-13, (1988)
[5]
Kumar, S., Mishra, N. M., and Mukherjee, P. S., 2005, "Additives Depletion and Engine Oil Condition – a Case Study," Industrial Lubrication and Tribology, 57(2), 69 (2005).
[6]
A. B.Vipper, I. I. Zadko, M. V. Ermolaev "Engine Oil Ageing Under Laboratory Conditions" Lubrication Science, 14(3), 363(2006).
[7]
E. T Denisov, G. I. Kovalev, Oxidation and stabilization of jet fuels. P. 155, (1993),
[8]
Adiwar, , B. D.Bans, Proceedings of the 5th International Conference on Long Term Storage Stability of Liquid Fuels, National Technical Information Service, Springfield, Vol. 2, 1995, P649.
[9]
Rajiv Banavali and Bharati Chheda, Rohm and Haas Company chemical basis of diesel fuel stabilization by TAPA, Deer Park, Texas, 2000.
[10]
S.K Ivanov,M.J. Abd Alghani, Z. Kalitchin " Isolation and characterization of NNC from Iraqi Crude oil' Institute of organic petroleum chemistry, Bulgaria, Sofia, 1993, P. 75
[11]
C. P. Henry "The du Pont F-21 Accelerated stability test" American Society for Testing and Materials, 1981, p 22.
[12]
ASTM D2274-14, Standard Test Method for Oxidation Stability of Distillate Fuel Oil (Accelerated Method), ASTM International, West Conshohocken, PA, 2014,
[13]
S. Masoudian, H. Yahyaei, Oxidation of alcohols with hydrogen peroxide catalyzed by supported porphyrins. Indian J. Chem. 50(A), 1002 (2011).
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