Antibacterial and Anti-Fungal Activity of Copper and Nickel Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants
International Journal of Biomedical Science and Engineering
Volume 6, Issue 4, December 2018, Pages: 70-78
Received: May 23, 2018;
Accepted: Jun. 5, 2018;
Published: Mar. 2, 2019
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Mostafa E. Hendawy, Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mohammed F. Zaky, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Metal nanoparticles have attracted considerable interest particularly because of the size dependence of physical and chemical properties and its enormous technological potential. Among different metal nanoparticles, Copper and Nickel nanoparticles have attracted great attention. Grinding method is used to synthesize Copper and Nickel nanoparticles. In this paper, the new cationic Thiol polyurethane surfactants with different alkyl chain length were synthesized (PQ8, PQ10 and PQ12). The chemical structure of the synthesized surfactants was confirmed using infra-red spectroscopy (IR) and proton nuclear magnetic resonance spectroscopy (1H-NMR). The nanostructure of the synthesized surfactant with Copper and Nickel nanoparticles with diameters ranging from 10 to 55 nm was prepared and characterized using ultra violet spectrophotometer (UV), infra-red spectroscopy (IR) and transmission electron microscope (TEM). The results declare formation and stabilization of Copper and Nickel nanoparticle using synthesized cationic surfactants. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with Copper and Nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.
Mostafa E. Hendawy,
Mohammed F. Zaky,
Antibacterial and Anti-Fungal Activity of Copper and Nickel Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants, International Journal of Biomedical Science and Engineering.
Vol. 6, No. 4,
2018, pp. 70-78.
Shrikaant K, (2015), Biosynthesis and Characterization of Copper Metal Nanoparticles Using Ascorbic Acid. Chemical Science Transactions, 4: 922-926.
Pergolese B, Miranda Muniz M, Bigotto A, (2006), Study of the Adsorption of 1,2,3-Triazole on Silver and Gold Colloidal Nanoparticles by Means of Surface Enhanced Raman Scattering J. Phys. Chem. B 110: 9241–9247.
Toimil-Molares ME, Buschmann V, Dobrev D, Neumann R, Scholz R, Schuchert IU, Vetter J, (2001), Single-crystalline copper nanowires produced by electrochemical deposition in polymeric ion track membranes. Adv. Mater. 13: 62-69.
Toimio-Molares ME, Hohberger EM, Schaeflein C, Blick RH, Neumann R, Trautmann C, (2003), Electrical characterization of electrochemically grown single copper nanowires. Appl. Phys. Lett. 82, 2139-2147.
Subhankari I, (2013), Antimicrobial Activity of Copper Nanoparticles Synthesised by Ginger (Zingiber officinale) Extract. World Journal of Nano Science & Technology 2(1): 10-13.
Ki-Young Yoon, Jeong Hoonm Byeon, Jae-Hong Park, Jungho Hwang (2007), Susceptibility constants of Escherichia coli and Bacillus subtilis to silver and copper nanoparticles. Science of the Total Environment, 373: 572-575.
Raffi M, Mehrwan S, Bhatti TM, Akhter JI, Hameed A, Yawar W, (2010), Investigations into the antibacterial behavior of copper nanoparticles against Escherichia coli. ann Microbiol, 60: 75–80.
Rispoli F, Angelov A, Badia D, Kumar A, Seal S, Shah V, (2010), Understanding the toxicity of aggregated zero valent copper nanoparticles against Escherichia coli. J Hazard Mater 180:212–216.
Ravishankar Rai V, Jamuna Bai A, (2011), Nanoparticles and Their Potential Application as Antimicrobials, Science against Microbial Pathogens: Communicating Current Research and Technological Advances. In: Méndez-Vilas, A., Ed., Formatex, Microbiology Series, No. 3, Vol. 1, Spain, 197-209.
Negm NA, Mohamed AS, (2008), Synthesis, characterization and biological activity of sugar-based gemini cationic amphiphiles. J Surfact Deterg 11:215-221.
Shokry SA, El Morsi AK, Sabaa MS, Mohamed RR, El Sorogy HE, (2015), Synthesis and characterization of polyurethane based on hydroxyl terminated polybutadiene and reinforced by carbon nanotubes. Egypt J Petrol 24:145–54.
Negm NA, Morsy SMI, (2005), Corrosion inhibition of triethanolammonium bromide mono-and dibenzoate as cationic inhibitors in an acidic medium. J Surfact Deterg 8:283-287.
Zaki MF, Badawi AM, Sabbah IA, Abdelghani RA, Hendawy ME, (2015), Synthesis, Characterization and Surface Activities of Cationic Polysaccharide (Aloe) Schiff Base Surfactants. J Surfact Deterg 18:455-461.
Negm NA, El Hashash MA, Youssif MA, Ismail EA, Abdeen ZI, Abdel Rahman NR, (2017), Novel Nonionic Polyurethane Surfactants and Ag Nanohybrids: Influence of Nonionic Polymeric Chains. J Surfact Deterg 20:173-182.
Saleh N, Khowdiary M, Badawi AM, (2014), Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co(II), Cu(II), or Sn(II) Chlorides, Tenside Surf. Det. 51: 4-15.
Sara Busi, Manu Lahtinen, Jussi Valkonen, Kari Rissanen, (2006), Crystal structures and thermal behavior of bis [dibenzyldimethylammonium] CuBr4, bis [dibenzyldimethylammonium] CuCl4 and bis [dimethyldi (2 phenylethyl) ammonium] CuBr4 crystallized from acetonitrile and dilute HX (XZCl or Br) solutions, Journal of Molecular Structure 794: 277–287.
Muanza DN, Kim BW, Euler KL, Williams L, (1994), Antibacterial and Antifungal Activities of Nine Medicinal Plants from Zaire. Int. J. Pharmacogn. 32: 337-345.
Azzam EMS, El-Frarrge AFM, Ismail DA, Abd-Elaal AA (2011) Enhancement of the surface activity for some monomeric and polymeric thiol surfactants using silver nanoparticles. J Disp Sci Technol 32:816–822.
Sulekh Chandra, Avdhesh Kumar, Praveen Kumar Tomar, (2014), Synthesis of Ni nanoparticles and their characterizations. Journal of Saudi Chemical Society, 18: 437–442.
Cukurovali A, Yilmaz I, Gur S, Kazaz C, (200), Synthesis, antibacterial and antifungal activity of some new thiazolylhydrazone derivatives containing 3-substituted cyclobutane ring. Eur. J. Med. Chem. 41: 201-207.
Negm NA, Morsy SMI, Said MM, (2005), Biocidal activity of some Mannich base cationic derivatives. Bioorg. Med. Chem. 13: 5921-5926.