Chemical and Biomolecular Engineering
Volume 2, Issue 4, December 2017, Pages: 180-183
Received: Oct. 10, 2017;
Accepted: Nov. 20, 2017;
Published: Jan. 2, 2018
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Kelly Bossardi Dias, Department of Lignocellulosic Materials, School of Engineering, São Paulo State University (UNESP), Campus of Itapeva, São Paulo, Brazil
Ricardo Marques Barreiros, Department of Lignocellulosic Materials, School of Engineering, São Paulo State University (UNESP), Campus of Itapeva, São Paulo, Brazil
For environmental reasons, both the preservation of traditional wood and the use of resistant wood species are subject to political and consumption restrictions. It is known that the effectiveness of traditional wood preservation systems is due to the biocidal effect of the products used, but, consequently, they pollute the environment. And this has generated the need to develop less aggressive condom treatments for health and the environment with sustainable principles. Thus, the aim of research has been to develop environmentally correct and effective products against the attack of biodeteriorating agents. A viable alternative that contains interesting inhibiting properties is Tall Oil, which is a natural renewable source oil. Tall Oil is an industrially generated by-product in the production of kraft pulp. This by-product is not a pure triglyceride compound, but a mixture of fatty acids, resin acids and unsaponess. The use of Tall Oil and its derivatives as a protective agent in wood has been considered promising. It can be used pure, whether crude or distilled; and even in mixtures with efficient biocides, but leachable as boron. However research is still needed including the characterization of Tall Oil products, the determination of the protective agent and the environmental aspects.
Kelly Bossardi Dias,
Ricardo Marques Barreiros,
Potentiality of Tall Oil as Preservative for Wood, Chemical and Biomolecular Engineering.
Vol. 2, No. 4,
2017, pp. 180-183.
COSTA, F., VALE, A. T., GONZALEZ, J. C., SOUZA, F. D. M. Durabilidade de madeiras tratadas e não tratadas em campo de apodrecimento. Floresta e Ambiente, v. 12, n. 1, p. 07 - 14, 2005.
PAES, J. B. MORESCHI, J. C., J. G. LELLES. Avaliação do tratamento preservativo de moirões d, e Eucalyptus viminalis Lab. e de bracatinga (Mimosa scabrella Benth.) pelo método de substituição de seiva. Ciência Florestal, v. 15, n. 1, p. 75-86. 2005.
SINGH, T., SINGH, A. P. A review on natural products as wood protectant. Wood Science Technology, n. 46, p. 851–870, 2012.
ROWELL, R. M. Chemical Modification: a non-toxic approach to wood preservation. In: ECOWOOD 2006 – International Conference on Environmentally, 2. Anai. p. 227-237, Oporto, Portugal, 2006.
KOSKI, A. Applicability of crude tall oil for wood protection. Departamento de Processos e de Engenharia Ambienta - Faculdade de Tecnologia - Universidade de Oulu, Finlândia, 2008. 104 p. Dissertação de Mestrado.
AASERUB, J.; LARNOY, E.; GLOMM, W. R. Alternative systems for wood preservation, based on treatment with silanes. In: BERGSTEDT, A. Proceedings of the 5th meeting of the Nordic-Baltic Network in Wood Material Science and Engineering. Copenhagen: Denmark, n. 43, p. 21-26, 2009.
HYVÖNEN, A., PILTONEN, P., NIINIMÄKI, J. Tall oil/water – emulsions as water repellents for scots pine sapwood. Holz als Roh-und Werkstoff, n. 64, p. 68-73, 2006.
TEMIZ, A., ALFREDSEN, G., EIKENES, M., TERZIEV, N. Decay resistance of Wood treated with boric acid and tall oil derivates. Bioresource Technology, n. 99, p. 2102-2106, 2008.
PANDA, Dr. H. Handbook on tall oil rosin production, processing and utilization. Asia Pacific Business Press Inc.: Delhi, India, 2013. [Google Scholar].
VÄHÄOJA, P., PILTONEN, P., HYVÖNEN, A. NIINIMÄRKI; J., KUOKKANEN, T. Biodegradability studies of certain wood preservatives in groundwater as determined by the respirometric bod oxitop method. Water, Air and Soil Pollution, n. 165, p. 313-324, 2005.
SALES, H. J. S. Esterificação seletiva para a separação de esteróis, ácidos resínicos e ácidos graxos do residuo oleoso de madeira (tall oil). Instituto de Química - Departamento de Química Orgânica, Universidade Estadual de Campinas, Campinas, 2007. 167 p. Tese de Doutorado.
TAILOR, S., KING, J. W. Fatty and resin acid analysis in tail oil products via supercritical fluid extraction-supercritical fluid reaction using enzymatic catalysis. Journal of Chromatographic Science, v. 39, p. 269-272, 2001.
KWON, H. S., MOON J. H., LEE U. D., YOON J. J., WALSUM G. P. V., UM B. H. Fractionation and gasification of black liquor derived from kraft pulping. Journal of Industrial and Engineering Chemistry, n. 34, p. 122–129, 2016.
RAMOS, L. P., GARCIA, J. N. Tall oil: uma fonte de breu ainda pouco usada no país. Informativo ARESB, n. 93, nov. 2007.
ALFREDSEN, G., FLAETE, P. O., TEMIZ, A., EIKENES, M., MILITZ, H. Screening of the efficacy of tall oils against Wood decaying fungi. The internacional research group on wood preservation. IRG/WP 04-30354, 2004.
ANITA, S. H., FATRIASARI, W., ZULFIANA, D. Utilization of biopulping black liquor as preservative to fungal attack on jabon wood (Anthocephalus cadamba Miq.). Teknologi Indonesia, n. 37, v. 3, p. 147-153, 2014.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). ASTM D1413: Standard method for accelerated laboratory test of natural decay resistance for woods. West Conshohocken: ASTM International, 2007.
DURMAZ, S., ERISIR, E., YILDIZ, U. C., KURTULUS, O. C. Using Kraft Black Liquor as A Wood Preservative. Procedia - Social and Behavioral Sciences. n. 195, p. 2177 – 2180, 2015.
JERMER J., BERGMAN Ö., NILSSON T. Fungus cellar and field tests with tall oil derivatives. Final report after 11 years’ testing. The international research group on wood preservation. Anais. 24th Annual Meeting in Orlando, Florida, USA, 16-21 May, 1993.
PAAJANEN, L., RITSCHKOFF, A. C. Effect of crude tall oil, linseed oil and rapeseed oil on the growth of decay fungi. The International Research Group on Wood Preservation, IRG/WP 02-30299, 2002.
PANOV, D.; TERZIEV, N.; DANIEL, G. Using plant oils as hydrophobic substances for wood protection. The International Research Group on Wood Preservation, IRG/WP 10-305550, 2010.
SCHULTZ, T. P.; NICHOLAS, D. D.; SHI, J. Water repellency and dimensional stability of wood treated with waterborne resin acids/TOR. The International Research Group on Wood Preservation, IRG/WP 07-40364, 2007.
SIVRIKAYA, H., CAN, A. Effect of weathering on wood treated with tall oil combined with some additives. Maderas. Ciencia y tecnología n. 18, v. 4, p. 723-732, 2016.