Novelpolyvinyl Chloride-Grafted-Poly (Ethylene Imine) Membranes for Water Treatment Applications: Synthesis and Membrane Characterizations
American Journal of Applied Chemistry
Volume 3, Issue 3-1, June 2015, Pages: 13-21
Received: Jan. 6, 2015;
Accepted: Jan. 8, 2015;
Published: Jan. 21, 2015
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Mohamed S. Mohy El-din, Polymer Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research & Technological Applications, New Borg Al-Arab City, Alexandria, Egypt
Mahmoud Abdel Ghafar, Chemistry Department, Polymers Department, National Research Center, Dokki, Giza, Egypt
Abd El GawadRabiea, Chemistry Department, Organic Chemistry, Faculty of Science, Ain Shams University, Cairo, Egypt
Hossam A. Tieama, Polymer Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research & Technological Applications, New Borg Al-Arab City, Alexandria, Egypt
Novel polyvinyl chloride grafted poly (ethylene imine), PVC-g-PEI membranes have been successfully synthesized by solvent evaporation technique using THF/ethanol as a solvent mixture. PEI was incorporated into PVC in different portions to increase the weak hydrophilicity of PVC membranes and to enhance physicochemical membranes surface properties. Membranes preparation conditions of PVC-g-PEI and their applications for water desalination process were optimized and discussed in details. PVC-g-PEI membranes were characterized by FTIR, morphologically using SEM, thermally using TGA&DSC, and mechanically using universal testing machine. Poly (ethylene glycol), PEG was then added to PVC-g-PEI membranes as a pore forming additive to increase pores density area and improve efficiency of the permeation flux of membranes. Addition of PEG portions increased permeation flux of PVC-g-PEI membranes (452 L/D/M2513 L/D/M2and605 L/D/M2) and salt rejection performance for mono membrane (33.5%, 30.8%and 27.4 %) for 3%, 2% and 1% NaCl solutions, respectively. Ion Exchange Capacity (IEC) for (PVC-g-PEI) membrane was 2.3 meq/gm and water uptake was 23%.All filtration experiments results were carried out at a trans-membrane pressure of 0.3 MPa at room temperature. The results showed that the permeate quality and quantity almost stable upon long run, thus PVC-g-PEI membranes can be used effectively for water treatment applications e.g. Nano-filtration and desalination.
Mohamed S. Mohy El-din,
Mahmoud Abdel Ghafar,
Abd El GawadRabiea,
Hossam A. Tieama,
Novelpolyvinyl Chloride-Grafted-Poly (Ethylene Imine) Membranes for Water Treatment Applications: Synthesis and Membrane Characterizations, American Journal of Applied Chemistry. Special Issue: Nano-Technology for Environmental Aspects.
Vol. 3, No. 3-1,
2015, pp. 13-21.
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