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Home / Journals / Chemistry & Chemical Engineering / American Journal of Applied Chemistry / Article
Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands
American Journal of Applied Chemistry
Volume 3, Issue 2, April 2015, Pages: 40-47
Received: Jan. 11, 2015; Accepted: Jan. 21, 2015; Published: Feb. 16, 2015
Volume 3, Issue 2, April 2015, Pages: 40-47
Received: Jan. 11, 2015; Accepted: Jan. 21, 2015; Published: Feb. 16, 2015
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Authors
Bitew Kassaw Dessie, University of Gondar, Department of Chemistry, Gondar, Ethiopia
Muluye Melak Zenebe, University of Gondar, Department of Chemistry, Gondar, Ethiopia
Atnafu Guadie Assefa, University of Gondar, Department of Chemistry, Gondar, Ethiopia
Abstract
Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
Keywords
Oxazoline, Metal Complexes, Spectroscopy
To cite this article
Bitew Kassaw Dessie,
Muluye Melak Zenebe,
Atnafu Guadie Assefa,
Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands, American Journal of Applied Chemistry.
Vol. 3, No. 2,
2015, pp. 40-47.
doi: 10.11648/j.ajac.20150302.12
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