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Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate
American Journal of Applied Chemistry
Volume 3, Issue 1, February 2015, Pages: 21-24
Received: Dec. 25, 2014; Accepted: Jan. 20, 2015; Published: Feb. 2, 2015
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Authors
Kazim Guliyev, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Afat Aliyeva, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Gulnara Ponomaryova, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Abasgulu Guliyev, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Dilbar Nurullayeva, Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
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Abstract
The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.
Keywords
Copolymerization, P-Vinylphenyl) Cyclopropyl Methylcinnamate, Photosensitivity
To cite this article
Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva, Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate, American Journal of Applied Chemistry. Vol. 3, No. 1, 2015, pp. 21-24. doi: 10.11648/j.ajac.20150301.14
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