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Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals
American Journal of Applied Chemistry
Volume 1, Issue 5, December 2013, Pages: 87-91
Received: Oct. 28, 2013; Published: Dec. 10, 2013
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Author
Khalil Khalaf Abid, Department of Chemistry, College of Science, Al – Mustansiryah University 10052 Baghdad – Iraq
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Abstract
Acyclic Schiff base ligand containing N2O3 donor atoms was synthesized by the reaction of 2,6 – diformyl – 4 – ter-butylphenol and 4 – aminoantipyrine in 1:2 molar ratio. The synthesized ligand (H1L) and Ln(III) complexes [Ln= LaIII, CeIII and GdIII] were characterized by1HN.M.R., 13CN.M.R., mass spectrometry, UV /Visible, FTIR, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. A seven coordinated complex obtained through N2O3 and two chloride atoms coordinated to metal ions.
Keywords
Lanthanides, Schiff Bases, 2, 6-Diformyl Phenol, Pentadentate Acyclic Ligand
To cite this article
Khalil Khalaf Abid, Pentadentate N2O3 Schiff Base Complexes of Rare Earth Metals, American Journal of Applied Chemistry. Vol. 1, No. 5, 2013, pp. 87-91. doi: 10.11648/j.ajac.20130105.12
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