Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode
World Journal of Applied Chemistry
Volume 3, Issue 1, March 2018, Pages: 28-31
Received: Feb. 23, 2018;
Accepted: Mar. 11, 2018;
Published: Apr. 9, 2018
Views 1515 Downloads 93
Yusuf Yildiz, Analytical Chemistry Research Department, Complete Analysis Laboratories, New Jersey, USA
Angela Jan, Analytical Chemistry Department, Whitehouse Labs/AMRI, New Jersey, USA
Sapan Patel, Whiting School of Engineering, John Hopkins University, Baltimore, USA
Follow on us
The Fluoride Ion Selective Electrode is an ion-selective sensor and will quickly and accurately measure fluoride ion activity rather than concentration in aqueous solutions. Fluoride ion activity depends on the solution total ionic strength and pH, and on fluoride complexing species. Adding an appropriate buffer provides a nearly uniform ionic strength background, adjust pH, and breaks up complexes so that, in effect, the electrode measures concentration. Pickling removes a thin surface layer from the stainless, using an acid solution, which is usually a hydrofluoric acid (HF) and nitric acid (HNO3), also called mixed acid. In this study, fluoride ion strength has been measured of pickling waste water from stainless steel by ion selective electrode. The results met the specification.
Pickling Stainless Steel Solution, Fluoride, Ion Selective Electrode
To cite this article
Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode, World Journal of Applied Chemistry.
Vol. 3, No. 1,
2018, pp. 28-31.
Copyright © 2018 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/
) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Bohler Welding Nordic AB. Pickling Handbook. Surface Treatment of Stainless Steel.
Technical Specification for the Fluoride Ion-Selective Electrode (ELIT 82221).
Y. Yildiz; Determination of Fluoride in tri-calcium phosphate (TCP) by Ion-Selective Electrode. International Journal of Development Research, Vol. 5, issue: 10, pp: 5704-5706, October, 2015.
Orion Research, Boston, MA.
Skoog/West/Holber, Analytical Chemistry an Introduction, Sixth Edition. Saunders Golden Sunburst Series. 1993, USA.
Prem N. Vijan and Baverly Aider, Determination of fluoride in vegetable by ion-selective electrode. American laboratory, December 1984.
Dionex, Application Note 209. Determination of Fluoride in Acidulated Phosphate Topical Solutions using reagent-Free Ion Chromatography.
Method for Determining the Concentration of Fluoride (F-) in Aqueous Solutions. NICO 2000. ELIT Brand Electrochemical Sensors.
Edens G. and Yildiz Y. Standard method for Determination of Fluoride in ARDE Pickling sample. Complete Analysis Laboratories, June 18, 2010. New Jersey, USA.
Fluoride Combination Ion Selective Electrode, Accument. Cat No: 13-620-528& 13-620-529 Published: 03/94.
Standard Methods for the Examination of Water &Wastewater, 21st Edition 2005. 4500-F-C Ion-Selective Electrode Method p: 4-84.
J. R. Sherman, Standard Method for Determination of Fluoride. Arde, Inc. New Jersey. 9-18- 2006.