Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature
International Journal of Science, Technology and Society
Volume 3, Issue 1-2, January 2015, Pages: 1-5
Received: Oct. 25, 2014;
Accepted: Oct. 30, 2014;
Published: Nov. 22, 2014
Views 3382 Downloads 148
Yasmin Akhtar, Department of Chemistry, University of Tabuk, Tabuk, Saudi Arabia
The present experimental investigation was carried out in order to explore the possible thermodynamic and interactions studies of D(+) fructose with mixed solvent of aqueous alkali metal halides at different molalities and constant temperature . Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+)fructose with aqueous NaCl ,KCl , MgCl2 and CaCl2 under different molalities and at 303K. The related and relevant parameters correlated to the present study such as adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0v and partial molal adiabatic compressibility, ф0Ks at infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion, ion-solvent, interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.
Thermodynamic and Interactions Studies of D(+) Fructose with Aqueous Alkali Metals Halides at Different Molalities and Constant Temperature, International Journal of Science, Technology and Society. Special Issue: Academic Research for Multidisciplinary.
Vol. 3, No. 1-2,
2015, pp. 1-5.
Y. Akhtar, J. international acad. Res. Multi Disipliry. , “Molecular and thermodynamic interaction of D(+) glucose with mixed solvent of electrolytes solutions at 303 K”, vol. 2 2014 pp 693-700.
Y. Akhtar, S. F. Ibrahim, Arabian , “Ultrasonic and thermodynamic studies of glycine in aqueous electrolytes solutions at 303 K”, J. Arabian Chem. Vol. 4 2011 pp 487- 490.
F. J. Millero, A. L. Surdo and C. Shiv, “Apparent molal volumes and adiabatic compressiblities of aqueous transition metals.” J. Phys. Com. Vol. 84 1980 pp 719-723.
S. S. Aswale, S.R. Aswalev and and R. S. Hajare, “Adiabatic compressibility intermolecular free length and acoustic relaxation time of aqueous antibiotic cefotaxime sodium” Indian J. Chem., vol.4 2012 pp2671-2677.
S. Thirumaran and J. K. Sabu, “Ultrasonic studies of interactions of some alkali halides in aqueous d-glucose solutions at varying molalities and temperature”, Journal Exp. Sci., Vol. 3 2012 pp 33-39.
M. J. Iqbal and M. A. Chaudhry, “ Volumetric and viscometric studies of drugs in aqueous medium at different temperature”, J. Chem. Engg. Vol. 54 2009 pp 2772-2776.
A. K. Nain and R. Pal. “ Study of solute- solute and solute -solvent interacttions of Threonine in aqueous glucose solutions at different temperatures by using volumetric ans viscometric methods”, J. Chem Thermodyn. , vol.104 2013; pp 60-98.
E. J Gonzalez, S. B. Bottini, S. Peeda and E. A. Macedo, “Liquid- Liquid equlibria of binary systems, Experimental data and Thermodynamic modeling using a group contribution equation of state” Fluid Phase Equil. Vol.362 2014 pp163-169.
M. J. Iqbal and M. Siddiquah, “ Partial molar volume of mefenamic acid in alcohol at temperature 293.15 and 313.15 K,” J. Braz. Chem. Soc. Vol.17 2006 pp727-735.
F. Ciotta, J. P. M. Truster and V. Vesovic, “ Extended hard - sphere model for the viscosity’’, Fluid Phase Equilib. Vol.363 2014 pp 239-247.
Y. Akhtar, “Volumetric and viscometric behavior of amino acids in aqueous metal electrolytes solutions at 308 K”, Fluid Phase Equil. Vol. 258 2007 pp125-131.
X. Jiang, C. Zhu and Y. Ma. “Volumetric and viscometric studies of amino acids in L-L-ascorbic acid aqueous solutions at temperature 293.15- 323.15 K”, J. Chem. Thermodyn. Vol.71 2014 pp 50-63..
R. K. Wadi and P. Ramasmi “Partial molal volumes and adiabatic compessiblities of transfer of glycine and D-L alanine from water to aqueous sodium sulphate at 288.15, 298.15 and 308.15 K”, J. Chem. Soc. Faraday Trans. Vol. 93 1997 243-247.
M. S. Hussain, T. K. Biswas, D. C. Kabiraz, M. N. Islam and M. E. Haque, “Studies on sodium dodecylsulphate in aqueous and in aqueous amino acids solutions”, J. Chem. Thermodyn. Vol.71 2014; pp 6-13.
I.L. Shulgin and E. Ruckenstein “ Relationship between preferential interac- tion of a protein in an aqueous mixed solvent and its solubility”, Biophys Chem. Vol. 118 2005 pp 128-34.
Vishnu D. , Y. Akhtar, J. D.Pandey, “Ultrasonic and Thermodynamic studies of Ternary solutions”, Acta Acoust. , Vol 84 1998 pp 976 981.