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Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance
Science Discovery
Volume 4, Issue 2, April 2016, Pages: 137-141
Received: May 19, 2016; Published: May 19, 2016
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Authors
Cai Jian-guo, Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Shi Hong-yan, Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Zhu Zhi-rong, Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
Shi Xiao-li, Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China
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Abstract
With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.
Keywords
Butene Hydration, Pores, Acid Resin, Catalyst, Reaction Performance
To cite this article
Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li, Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance, Science Discovery. Vol. 4, No. 2, 2016, pp. 137-141. doi: 10.11648/j.sd.20160402.23
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