Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film
American Journal of Materials Synthesis and Processing
Volume 2, Issue 2, March 2017, Pages: 17-23
Received: Mar. 11, 2017; Accepted: Mar. 23, 2017; Published: Apr. 24, 2017
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Authors
Siyamak Shahab, Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus; Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, Minsk, Belarus
Liudmila Filippovich, Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus; Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, Minsk, Belarus
Masoome Sheikhi, Young Researchers and Elite Club, Gorgan Branch, Islamic Azad University, Gorgan, Iran
Hooriye Yahyaei, Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, Iran
Maria Aharodnikova, Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus
Rakesh Kumar, Department of Applied Sciences, CTIT, CT Group of Institutions, Jalandhar (Punjab), India
Mehrnoosh Khaleghian, Department of Chemistry, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran
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Abstract
Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity). Thermal conductivity in a direction of orientation (λ) is higher than in a direction perpendicular orientations (λ).
Keywords
Polarizer Film, Dichroic Dye, Thermal Conductivity, Polarization Efficiency
To cite this article
Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, Rakesh Kumar, Mehrnoosh Khaleghian, Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film, American Journal of Materials Synthesis and Processing. Vol. 2, No. 2, 2017, pp. 17-23. doi: 10.11648/j.ajmsp.20170202.11
Copyright
Copyright © 2017 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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