Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table
American Journal of Physical Chemistry
Volume 2, Issue 3, June 2013, Pages: 52-59
Received: Jul. 16, 2013; Published: Aug. 20, 2013
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Vitaly Vitalevich Ovchinnikov, Department of General Chemistry and Ecology, Tupolev Kazan National Researching Technical University, Tatarstan, Russia
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Abstract
It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.
Keywords
Organometallic Compounds, Free Energy of Combustion, Free Energy of Formation, Entropy, Heat Capacity, Heat of Combustion Heat of Formation
To cite this article
Vitaly Vitalevich Ovchinnikov, Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table, American Journal of Physical Chemistry. Vol. 2, No. 3, 2013, pp. 52-59. doi: 10.11648/j.ajpc.20130203.11
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