Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance
Science Journal of Chemistry
Volume 4, Issue 5, October 2016, Pages: 61-68
Received: Aug. 27, 2016; Accepted: Sep. 21, 2016; Published: Oct. 11, 2016
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Authors
Fathelrahman Mohammed Soliman, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wu Yang, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Hao Guo, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wen Yao, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Mahgoub Ibrahim Shinger, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Ahmed Mahmoud Idris, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Emtenan Suliman Hassan, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Ali Mahmoud Alamin, Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
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Abstract
A novel oil highly absorptive resin was prepared by a suspension polymerization using 1-butyl -3- (2- methacryl) ethyl imidazolium hexafluorophosphate (BMIm)PF6-, methyl methacrylate (MMA), and butylacrylate (BA) as monomers, azobisisobutyronitrile as initiator, N, N methylenebis (acryl amide) (MBA) as crosslinking agent and polyvinyl alcohol (PVA) as dispersant and characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The effects of different polymerization technological parameters, such as the mass ratios of the monomers, the addition amounts of the initiator, the cross-linker and the dispersant, the polymerization temperature and time, on the oil absorbency of the high oil absorption resin P (BMIm-MMA-BA) copolymer were examined in detail. Under the optimal condition, the oil absorbency was about 25.6 g/g for benzene, 22.6 g/g for xylene, 32.3g/g for chloroform, and 30 g/g for carbon tetrachloride, respectively. The kinetic investigation indicated the oil absorption obeyed the pseudo-first-order kinetic equation.
Keywords
Ionic Liquids Monomer, Suspension Polymerization, High Oil-Absorption Resins, Oil Absorbency
To cite this article
Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Wen Yao, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Emtenan Suliman Hassan, Ali Mahmoud Alamin, Synthesis and Characterization of an Ionic Liquid Enhanced High Oil Absorption Resin of P (BMIm-MMA-BA) and Its Oil Absorption Performance, Science Journal of Chemistry. Vol. 4, No. 5, 2016, pp. 61-68. doi: 10.11648/j.sjc.20160405.12
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Copyright © 2016 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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