Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals
Science Journal of Chemistry
Volume 1, Issue 4, October 2013, Pages: 38-49
Received: Jul. 30, 2013; Published: Sep. 20, 2013
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Mahmoud Najim A. Al-Jibouri, Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Taghreed M. Musa, Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Mudeer Mubarak, Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Wessal M. al-Jibouri, Chemistry Department, college of Science, Al-Mustansiryah, Iraq
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A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.
PVC, Chelating Properties of Resin and 8-Hydroxyquinoline
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Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri, Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals, Science Journal of Chemistry. Vol. 1, No. 4, 2013, pp. 38-49. doi: 10.11648/j.sjc.20130104.11
Amit, B., Rawlins, J.W., Ray, P., Polymer Crafting and Crosslinking. JOHN WILEY & SONS, INC, (2009).
Agarry, S.E., Owabor, C.N. and Ajani, A.O. Modified Plantain Peel As Cellulose-Based Low-Cost Adsorbent for the Removal of 2,6-Dichlorophenol from Aqueous Solution: Adsorption Isotherms, Kinetic Modeling, and Thermodynamic Studies. Chemical Engineering Communications, (2013), (8), 1121-1147
Biji, B., D.S Kumar, Y. Yasunhida and A.Jayakrishnam, 2005." Chemical modification of poly (vinyl chloride) resin using poly (ethylene glycol) toimprove blood compatibility" Biomaterials", 26: 3495-3502.
Chen, Y., Y. Song, Y. Zhang and Lang. A tricobalt(II) coordination polymer incorporating in situ generated 5-methyltetrazolate ligands. Inorganic Chemistry Communications, 11: PP. 572-575, 2008.
Chereminisoff P, and EllerpuschF(1978), Chem Interaction, Hand book, Us. Pp 281-329 D.Feng, C.Aldrich, H.Tan H, MineralsEngineering, (2001) 13, pp.623-642
D.N.Sathyanaryan" Electronic Absorption spectroscopy and Related Techniques '1st. ed. New Delhi (2001).
Dyer J .R" Applications of Absorption spectroscopy of organic compounds prentice H all of India, 2nd ed ., New Delhi (1971),33.[Kuman K., Chang C.A. and Tweedle, "The investigation of complex stability of complexes using Bjerrum method", Inorg. Chem., Vol.32, p. 587. 1995.
E.M. pratic , J.N. barbe, H.D. Juneja, L.J paliwel , Europ. Polym.J (2007), 43.pp (5000-5010).
Emad Y. Synthesis, spectroscopic studies and fungicidal activity of some dioganotin(IV) with 2[(pheylcarbonyl) amino] propanoato. Journal of King Saud University, 24: PP.167-170, 2012.
F. Vernon ,K.N.Nyo,AnolgChem.Act. 93(1977)203. Goswami A, Singh AK, VenKa, 8-Hydroxy quniolineanchored to silica gel via new moderate sizelinkaTalanta 60 B (2003):1141-1154
GurnuleW.B ,paliwalLj.Kharatrj.Ssynthsis. React. Inorg.Met.Org.Chem.(2001):31(8), pp.1453- 1477
Gupta RH, Zade AB, GurnuleW.B,J.UHraSci phys. SCi. (2007);19(3), 359-366. H.FreundlichJournal of physical chemistry,(1906) 57, pp.385-470
H.B. Pancholi, M.M.Patel".J.Polym. l" Ion –exchange properties of tetra polymers with bivalent Metal ions perform. J.polym (1991), 3, pp. 257-262.
HayaticFilik, MicrochimActa (2002), 140, pp.205-210
K. Nakamato "Infrared and Raman Spectra of Inorganic and coordination compound " Willey Interscience New York(1978).
Langmuir, J. Am. Chem . Soc.(1918), 40, pp. 1361-1403
Ling P.S, Paliwal ;L J and Juneja H.D. Proc. Nat, Acad. Sci. (2001), 71(A), 205
Lutfar M.R, Eur.poly.J.(02000, 36, 2105.
Mhamdi, M., Galai, H., Mnasri, N., Elaloui, E. and Trabelsi-Ayadi, M. (2013), Adsorption of lead onto mectite from aqueous solution. Environmental Science and Pollution Research, 20 (3), 1686-1697.
M.M,Jadho, L.J. Paliwal ,N.S. Bhcve, J.App. polym. Sci., (2005), 109, 1606- 1610
N.Raman , S.R Johnson and A.Sukthicevel, J. coord. Chem.62(2009), 691.
Moulay, S. Chemical modification of poly(vinyl chloride)-Still on the run. Progress in Polymer Science, 35, PP. 303-331, 2010
Patel J.R, Sutariya D.H and Patel M.N, React. Polym. (1995), 25, 17
Pahel .J R, Mutariya DH and Patel MN, Rect. Polymer.1995, 25,17
P.a.Dhakite and W.B.Gurnule ,Eurp.J. of chem. 8(3) ,2011).pp.1186-1190
R. C. De Geiso, L. G. Donaruma, E.A. Tomicchelatinon ion polymer , Anal . Chem . (1962) 34, pp,. 845- 847)
Raesh, N, J, Appl. Polym,Sci.(2011)108, pp.747-756
R.H. Coupta, A.B.Zade , W.B. Gurnule, J, Appl. Polym,(2008), 109, 3315-3320
R.N.singru ,W.B.Gumule, J. of Thermal Analysisandgalorimety .(2010) ,100: 1027-1036.
S.Chandara , S.D. Sharma, Transition Met. Chem. 27 - (2002) ]732.
S.S. Rahangdale, A.B. Zade, W.B. Gurnule, J. Appl. Polym. Sci. 108(2008), pp. 747-756.
S.S. Rahaujclale ,A.B.Zade, W.B.Gurnule (2009), chelation Ion exchange properties of resins , E.J. chem. 6, pp.835-843).Roth, E., Mancier, V. and Fabre, B. (2012), Adsorption of cadmium on different granulometric soil fractions: Influence of organic matter and temperature. Geoderma, 189), 133-143
Sharma, R.K" Design, Synthesis and Application of chelatingpolymers for separation and Determination of trace and toxic metal ion"s (2001), Pure Appl. Chem. 73(1), pp.181-186 V.V Haiwase, A.B.Kalambe, K.M.Khedkar and S.D.Deosarkar, Europ. J. of chem., 7(1), pp.287-290.
X. Liu, H. Chen, Ch. Wang, R. Qu, Ch. Ji, Ch. Sun, Q. Xu, Adsorption properties of amidoximated porous acrylonitrile/methyl acrylate copolymer beads for Ag(I), Polym.Advan.Technol, 2010, doi:10.1002/pat.1714.
M. Barkat, D. Nibou, S. Chegrouche, A. Mellah, The positive value of ΔS° reflects the affinity of Hg(II) for the resins used. Kinetics and thermodynamics studies of chromium(VI) ions adsorption onto activated carbon from aqueous solutions, Chem. Eng. Process. 48 (2009) 38–47.
L. Deng, Y. Su, H. Su, X. Wang, X. Zhu, Sorption and desorption of lead (II) from wastewater by green algae Cladophorafascicularis, J. Hazard. Mater.(2007), 143 pp.220–225.
W.J. Weber Jr., J.C. Morris, Removal of Biologically-Resistant Pollutants from Waste Waters by Sorption. Advances in Water Pollution Research, Pergamon Press, New York, 1962, pp. 231–266.
I. Langmuir, J. Am. Chem. Soc. 40 (1918) 1361.
H.M.F. Freundlich, Z. Phys. Chem. 57 (1906) 385.
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