Synthesis, Characterization and Theoretical Evaluation of the Transition Metal Complexes of 2, 6-Diacetylpyridine -Derived N5-Acyclic Ligands
Science Journal of Chemistry
Volume 1, Issue 2, June 2013, Pages: 14-20
Received: May 11, 2013;
Published: Jun. 10, 2013
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Mahmmod Al-Jubori, Chemistry Department, College of science, Al-Mustansyria University, Iraq
Omar Hamad Shehab AL-Obaidi, Chemistry Department, Women Education College, Al-Anbar University, Iraq
A series of transition elements complexes with [2, 6-diacetimino-pheylenediamine –[2, 2,diyl] pyridine ]of the general formula [MLCl]Cl, M= Zn(II), Cd(II), Hg(II) and [CrLCl]Cl2, respectively have been synthesized and fully characterized on the bases of C.H.N.M, elemental analysis, 13C NMR, UV- Visible and FTIR spectra, in addition the structure of complexes was characterized by magnetic moments and molar conductance in DMSO solution, and molar ratio of metal were also determined. The obtained data of spectra in conjugation with microelemental analyses suggested the octahedral symmetry for all the complexes since the molar ratio(M: L) is 1:1, and the newly ligand behaved as neutral pentadentate through four nitrogen atoms of NH2,C=N and pyridine ring on the basis of infrared spectroscopy and other analysis of molar conductance and magnetic moments for solid complexes. A theoretical treatment of the formation of complexes in the gas phase was studied, this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semi-empirical calculations.
Omar Hamad Shehab AL-Obaidi,
Synthesis, Characterization and Theoretical Evaluation of the Transition Metal Complexes of 2, 6-Diacetylpyridine -Derived N5-Acyclic Ligands, Science Journal of Chemistry.
Vol. 1, No. 2,
2013, pp. 14-20.
M.Tyagi and Chandra (2012), ORen Journal of Inorg.Chem.2, pp 41-48
Mishra, D. Nastar s., Drew, M.G.B. and Gattopadhyay S.K.(2006), Inorg.chimica Actr.359, 585-592
Raja N. and Ramesh R. (2010), spectrochimica Acta A, 75, pp.713-718
Chandra S., Tyagi M.and Agrawal , S.(2010), journal of Saudi chem.Soc. 15, pp.49- 54.
Sharma K., Singh, Fahnui, N. and Singh ,R.V,(2010) Spectrachimica Acta A, 75, pp. 422-427
FerraZ,K.O, Waradell, S.M.SVand Beraldo H.(2009),spectrachimica Acta A,737, Pp.140-145.
D.P.singh , S.Nupar, B.p.Yadar and V. B.rara (1997) polyhedron.16 (13), pp.2229-2232
S.A.Ali , soliman, M.M.Aboaly, R.M.Ramadam, J.Coord.chem.55(2002),1161
R.M.Sliverstin ,G.c.Bassler, T.C. Morill, spectroscopic Identification of organic compounds 4thed.,Wiley, New York(1981)].
K.Nakmoto, Infarred and Raman spectra of Inorganic and coordination compounds, 4thed, wiley, New York(1986).
Ferraro, J.R"Low frequency Vibration of Inorganic and coordination compound Plenum press, New York (1977).
Ayed , S.al.Shilri(2004), Synthesis, charactization and thermal analysis of some new metal complexes of poly dentate Schiff base spectra chimica Acta, partA, 60, 1189-1192].
A.B.P.Lever "Electronic spectra of Inorganic and coordination compounds "Elserier (1968).
D.wived, r., Sing V.Falimi N, Singh R.V.(2003)]Int.Chem.J.Sci, (2)p.233.
Clark, R.J.H. and Williams., C.S. Inorganic chem(1965), 4,350
Solooman , L..D, Kessling , G.Mobilitition of cation –macrocyclic Ligand complexes , pure Appl. Chem.(1993), 65(7),1533
R.S.Josey phus.C.J. Dhanara j and M.S Nair Transition Met Chem.(2006), 31, 699.
E.A. Canpolat Y. and M.Kayes, transition .Met.Chem.(2006), 31, 653.16.
D.P.Singh and etal polyhedron (1977),16(13) pp.2229-2232